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81.
Xiao-Fang Song Jiang-Tao Qin Ting-Ting Li Guo Liu Xiang-Xiang Xia Yue-Sheng Li Yi Liu 《应用聚合物科学杂志》2020,137(13):48516
Enriched selective adsorption-photocatalytic activity of Poly (vinyl alcohol)/Polyaniline/TiO2 (PVA/PANI/TiO2, noted as PAT) recyclable hydrogel photocatalyst with 3D structures were prepared by self-assembling and electron beam radiation crosslingking method. TiO2 nanoparticles were successfully introduced into the 3D matrix of the PVA/PANI hydrogel and manifested by FTIR, TG, XRD, XPS, and SEM-EDS. The microstructure of PAT was characterized further by SEM, TEM, and BET. The highly selective adsorption-photocatalytic activity of PAT was tested by the degradation of cationic or anionic dye and reduction of heavy metal ion in a closed and flow system under UV light irradiation. The results showed that PAT had a highest selective adsorption-photocatalytic performance at the appropriate content of PVA (10 wt %), TiO2 (15 wt %) and suitable radiation dose (50 kGy), which could be attributed to the synergistic effect of excellent selective adsorption and effective photocatalytic degradation. The mechanism of selective adsorption-photocatalytic on PAT was revealed synchronously in this study. Particularly, the novel PAT photocatalyst with 3D network structure also affords ease of separation and recycling, which is beneficial to water purification in a flow system. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48516. 相似文献
82.
Jing Li Ping Liu Yan Qu Tingdi Liao Bin Xiang 《International Journal of Hydrogen Energy》2018,43(5):2601-2609
The number of exposed active sites in a catalyst plays a key role in determining its catalytic performance. However, the aggregation effect in nanostructured catalysts causes much less reactive sites exposed. In this paper, we report a novel structure of WSe2/rGO with highly exposed WSe2 active edge sites by uniformly imbedding the rGO between each WSe2 nanosheets. With the introduction of rGO, the electron transport property of the WSe2/rGO hybrid structure has also been enhanced. The structure and composition of the samples were investigated by the X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy and transmission electron microscopy. Our electrochemical characterizations confirm that the WSe2/rGO hybrid structure exhibits enhanced electrochemical catalytic performance with a Tafel slop of 85 mV/dec for HER, much smaller than that of the pure WSe2. 相似文献
83.
The titanium carbides are potential candidates to achieve both high hardness and refractory property. We carried out a structural search for titanium carbides at three pressures of 0 GPa, 30 GPa and 50 GPa. A phase diagram of the Ti-C system at 0 K was obtained by elucidating formation enthalpies as a function of compositions, and their mechanical and metallic properties of titanium carbides were investigated systematically. We also discussed the relation of titanium concentration to the both mechanical and metallic properties of titanium carbides. It has been found that the average valence electron density and tractility improved at higher concentrations of titanium, while the degree of covalent bonding directionality decreased. To this effect, the hardness of titanium carbide decreases as the content of titanium increases. Our results indicated that the titanium content significantly affected the metallic properties of the Ti-C system. 相似文献
84.
Haiyi Peng Haishen Ren Mingzhao Dang Yi Zhang Xiaogang Yao Huixing Lin 《Ceramics International》2018,44(6):6527-6532
Ca0.9La0.067TiO3 (abbreviated as CLT) ceramics doped with different amount of Al2O3 were prepared via the solid state reaction method. The anti-reduction mechanism of Ti4+ in CLT ceramics was carefully investigated. X-ray diffraction (XRD) was used to analyze the phase composition and lattice structure. Meanwhile, the Rietveld method was taken to calculate the lattice parameters. X-ray photoelectron spectroscopy (XPS) was employed to study the valence variation of Ti ions in CLT ceramics without and with Al2O3. The results showed that Al3+ substituted for Ti4+ to form solid solution and the solid solubility limit of Al3+ is near 1.11 mol%. Furthermore, the reduction of Ti4+ in CLT ceramics was restrained by acceptor doping process and the Q × f values of CLT ceramics were improved significantly. The CLT ceramic doped with 1.11 mol% Al2O3 exhibited good microwave dielectric properties: εr = 141, Q × f = 6848 GHz, τf = 576 ppm/°C. 相似文献
85.
86.
阶梯溢流坝面坡度对一体化消能工水力特性的影响 总被引:1,自引:1,他引:0
为探求高水头、大单宽流量下坝面坡度对一体化消能工水力特性的影响,以阿海水电站为原型,采用三维k-ε双方程紊流模型,引入水气两相流VOF计算方法,利用几何重建格式来迭代生成自由水面,对1∶0.80、1∶0.75、1∶0.65三种阶梯面坡比进行数值模拟研究。结果表明:①最大负压值均位于首级阶梯立面凸角下1/4附近,并随坡度增加而增大。坡度为56.98°时,最大负压值为61.02 kPa,超过了6×9.81 kPa。②水流空化数在宽尾墩水舌出口位置出现最小值,空化数随坡度变陡而减小。坡度为56.98°时,空化数最小为0.358。坡度为51.34°时,空化数最大,为0.381。③随着阶梯溢流坝坝面坡度变缓,消力池最大临底流速增大。当坡度为51.34°时,消力池最大临底流速最大,达到26.84 m/s,超过了25 m/s,易发生冲磨破坏。当坡度为56.98°时,消力池最大临底流速最小,为24.00 m/s。消力池尾坎前最大临底流速随坡度增加而减小,坡度为56.98°时最小,为9.63 m/s;坡度为51.34°时,消力池尾坎前最大临底流速最大,为9.96 m/s。④坡度的变化对一体化消能工消能率的影响不大,坡度从51.34°增加到56.98°,消能率只提升0.15%。 相似文献
87.
Li Li Liao Fucheng Ren Zhenqin 《International Journal of Control, Automation and Systems》2020,18(3):719-729
International Journal of Control, Automation and Systems - This paper discusses the robust preview control problem for uncertain discrete-time systems, where future reference and disturbance... 相似文献
88.
Here, highly‐oriented poly(m‐phenylene isophthalamide)/polyacrylonitrile multi‐walled carbon nanotube (PMIA/PAN‐MWCNT) composite nanofiber membranes with excellent mechanical strength and thermal stability are successfully produced using electrospinning. It is demonstrated that the cooperation of multi‐walled carbon nanotubes (MWCNT) and high‐speed rotating collection is beneficial to the acquisition of highly oriented fibers and effectively improves the mechanical strength of the membrane along the orientation direction. Specifically, the tensile stress of poly(m‐phenylene isophthalamide)/polyacrylonitrile (PMIA/PAN) membrane is enhanced significantly from 10.6 to 20.7 MPa, benefiting from the highly oriented alignment of the fibers as well as the reinforcing effect of MWCNTs on the fibers. Furthermore, the stressing process of single fiber and fiber aggregates is carefully simulated, and the influence of MWCNTs on the mechanical properties of PMIA/PAN‐MWCNT membranes is analyzed comprehensively, providing a meaningful auxiliary means for the study of mechanical properties. In addition, the composite nanofiber membrane has the advantages of both PMIA and PAN, possessing high temperature resistance, flame‐retardancy, and chemical stability, for an ideal high‐temperature material. In short, the as‐prepared PMIA/PAN‐MWCNT composite membrane with excellent comprehensive property emerges a promising application in many fields, especially in high‐tech. 相似文献
89.
研究聚酰亚胺纤维、芳纶纤维、玄武岩纤维、聚萘二甲酸乙二醇酯(PEN)纤维和聚亚苯基苯并二噁唑(PBO)纤维的工业丝性能及浸胶帘线的力学性能和粘合性能。结果表明:聚酰亚胺纤维和PBO纤维具有较高的强力和模量;聚酰亚胺纤维通过参考芳纶纤维的浸胶液配方进行浸胶处理,帘线与橡胶粘合性能良好;PEN纤维可以直接使用聚对苯二甲酸乙二酯(PET)纤维的浸胶方法进行处理;玄武岩纤维采用优化浸胶液配方进行浸胶处理,完全可以实现帘线与橡胶的良好粘合;PBO纤维采用目前现有浸胶方法较难进行表面接枝处理,与橡胶粘合性能较差。 相似文献